|
|
[biotin_carboxyl-carrier-protein_dimer]-N6-biotinyl-L-lysine + HCO3- + ATP <=> phosphate + [carboxyl-carrier_protein_dimer]-N6-carboxybiotinyl-L-lysine + ADP + H+
|
6.3.4.14
biotin carboxylase
|
–
|
|
MetaCyc:
BIOTIN-CARBOXYL-RXN
|
|
|
|
HCO3- <=> H2O + CO2
|
1.6.5.4
monodehydroascorbate reductase (NADH)
4.2.1.1
carbonic anhydrase
|
–
–
|
|
BRENDA:
BR3383
KEGG:
R00132;
R10092
MetaCyc:
CARBODEHYDRAT-RXN;
RXN0-5224
SABIO-RK:
703
|
|
|
|
propionyl-CoA + NADP+ <=> acryloyl-CoA + NADPH + H+
|
1.3.1
1.3.1.84
acrylyl-CoA reductase (NADPH)
1.3.1.95
acrylyl-CoA reductase (NADH)
|
–
–
–
|
|
BRENDA:
BR49115
KEGG:
R00919
MetaCyc:
RXN-9087
SABIO-RK:
1239
|
|
|
|
3-hydroxypropionate + NADP+ <=> malonate_semialdehyde + NADPH + H+
|
1.1.1
1.1.1.2
alcohol dehydrogenase (NADP+)
1.1.1.276
serine 3-dehydrogenase (NADP+)
1.1.1.298
3-hydroxypropionate dehydrogenase (NADP+)
|
–
–
–
–
|
|
BRENDA:
BR49111
KEGG:
R09289
MetaCyc:
RXN-8974
SABIO-RK:
12224
|
|
|
|
malonate_semialdehyde + CoA + NADP+ <=> malonyl-CoA + NADPH + H+
|
1.2.1.18
malonate-semialdehyde dehydrogenase (acetylating)
1.2.1.75
malonyl-CoA reductase (malonate semialdehyde-forming)
|
–
–
|
|
BRENDA:
BR49113
KEGG:
R00740
MetaCyc:
RXN-8963
|
|
|
|
beta-methylmalyl-CoA <=> 2-methylfumaryl-CoA + H2O
|
4.2.1.148
2-methylfumaryl-CoA hydratase
4.2.1.153
3-methylfumaryl-CoA hydratase
|
–
–
|
|
BRENDA:
BR51001
KEGG:
R05076
MetaCyc:
RXN-8960
|
|
|
|
3-hydroxypropionate + ATP + CoA <=> bithionol + AMP + diphosphate
|
6.2.1.17
propionate---CoA ligase
6.2.1.36
3-hydroxypropionyl-CoA synthase
6.2.1.40
4-hydroxybutyrate---CoA ligase (AMP-forming)
|
–
–
–
|
|
BRENDA:
BR49558
KEGG:
R09286
MetaCyc:
RXN-9086
|
|
|
|
2-methylfumaryl-CoA <=> 3-methylfumaryl-CoA
|
5.4.1.3
2-methylfumaryl-CoA isomerase
|
–
|
|
BRENDA:
BR51008
KEGG:
R09283
MetaCyc:
RXN-13230
|
|
|
|
(3S)-citramalyl-CoA <=> pyruvate + acetyl-CoA
|
2.3.1.182
(R)-citramalate synthase
4.1.3.25
(S)-citramalyl-CoA lyase
|
–
–
|
|
BRENDA:
BR3372
KEGG:
R00237
MetaCyc:
CITRAMALYL-COA-LYASE-RXN
|
|
|
|
(3S)-citramalyl-CoA <=> 3-methylfumaryl-CoA + H2O
|
4.2.1.148
2-methylfumaryl-CoA hydratase
4.2.1.153
3-methylfumaryl-CoA hydratase
|
–
–
|
|
BRENDA:
BR51057
KEGG:
R09282
MetaCyc:
RXN-8965
|
|
|
|
beta-methylmalyl-CoA <=> glyoxylate + propionyl-CoA
|
4.1.3.24
malyl-CoA lyase
|
–
|
|
BRENDA:
BR50832
KEGG:
R00934
MetaCyc:
RXN-8961
|
|
|
|
acetyl-CoA + [carboxyl-carrier_protein_dimer]-N6-carboxybiotinyl-L-lysine <=> malonyl-CoA + [biotin_carboxyl-carrier-protein_dimer]-N6-biotinyl-L-lysine
|
2.1.3.15
acetyl-CoA carboxytransferase
|
–
|
|
MetaCyc:
RXN0-5055
|
|
|
|
bithionol <=> acryloyl-CoA + H2O
|
4.2.1
4.2.1.116
3-hydroxypropionyl-CoA dehydratase
4.2.1.17
enoyl-CoA hydratase
|
–
–
–
|
|
BRENDA:
BR49125
KEGG:
R03045
MetaCyc:
RXN-6383
SABIO-RK:
2892
|
|